Corrosivity Assessment of Hybrid Amine-Local Solvent Blends in Natural Gas Sweetening

Authors

  • Tare Caroline Gillow Department of Petroleum and Gas Engineering, Nigeria Maritime University Okerenkoko, Delta State, Nigeria
  • Ipeghan J. Otaraku Centre for Gas Refining and Petrochemical Engineering,University of Port Harcourt Choba, Rivers State, Nigeria
  • Peter O. Muwarure Department of Chemical Engineering, University of Port Harcourt Choba, Rivers State, Nigeria
  • Johnson Nnadikwe Centre for Gas Refining and Petrochemical Engineering,University of Port Harcourt Choba, Rivers State, Nigeria

Keywords:

Corrosion,Natural Gas, Sweetening, Agricultural Waste.

Abstract

 This study optimised hybrid amine-local solvent blends for sustainable natural gas sweetening, tackling corrosion and environmental footprint of imported monoethanolamine (MEA). The study designed and evaluated an absorption process using blends of MEA with solvents derived from agricultural waste Plantain Peel Ash Extract (PPAE).  The study integrates computational corrosion prediction models from the outset, acknowledged and addressed a common deficiency, performance optimisations were evaluated with critical material compatibility constraints from the beginning.Corrosivity assessment predicted a manageable corrosion rate of 0.29 mm/year for the optimal blend, within acceptable limits for carbon steel with standard inhibition. The study conclusively establishes the 50/50 MEA/PPAE hybrid solvent as a technically robust and  environmentally superior alternative. It successfully valorises local agricultural waste, reduces dependency on imported chemicals, and aligns with Nigeria's local content policy and global sustainability goals, offering a viable pathway for greener and more cost-effective natural gas processing.

 

References

Abotaleb, A., Gladich, I., Alkhateeb, A., Mardini, N., Bicer, Y., & Sinopoli, A. (2022). Chemical and physical systems for sour gas removal: An overview from reaction mechanisms to industrial implications. Journal of Natural Gas Science and Engineering, 106, 104755.

Adegunju, S. A., Awad, M. R., Berrouk, A. S., & Dara, S. (2018). Tackling increased CO2 concentration in feeds for existing acid gas removal units: A simulation study based on a customized CO2 kinetics model. Separation Science and Technology, 53(12), 2004–2015. https://doi.org/10.1080/01496395.2018.1454478

Alnili, F., & Barifcani, A. (2018). Simulation study of sweetening and dehydration of natural gas stream using MEG solution. The Canadian Journal of Chemical Engineering, 96(9), 2000–2006. https://doi.org/10.1002/cjce.23146

Aromada, S. A., & Kvamme, B. (2019). Impacts of CO2 and H2S on the risk of hydrate formation during pipeline transport of natural gas. Frontiers of Chemical Science and Engineering, 13(3), 616-627.

Berchiche, A., Guenoune, M., Belaadi, S., & Léonard, G. (2023). Optimal energy integration and off-design analysis of an amine-based natural gas sweetening unit. Applied Sciences.

Borhani, T. N., Afkhamipour, M., Azarpour, A., Akbari, V., & Ramasamy, M. (2015). Role of solvents in CO2 capture processes: A review. International Journal of Greenhouse Gas Control, 41, 261–279. https://doi.org/10.1016/j.ijggc.2015.07.007

Chan, Y. H., Lock, S. S. M., Wong, M. K., Yiin, C. L., Loy, A. C. M., Cheah, K. W., ... & Lam, S. S. (2022). A state-of-the-art review on capture and separation of hazardous hydrogen sulphide (H2S): Recent advances, challenges and outlook. Environmental Pollution, 314, 120219.

Esmaeili, A., Yoon, T., Atsbha, T. A., & Lee, C. J. (2023). Rate-based modeling and energy optimization of acid gas removal from natural gas stream using various amine solutions. Process Safety and Environmental Protection, 177, 643–663. https://doi.org/10.1016/j.psep.2023.07.031

Farooqi, A. S., Ramli, R. M., Lock, S. S. M., Hussein, N., & Shahid, M. Z. (2022). Simulation of natural gas treatment for acid gas removal using the ternary blend of MDEA, AEEA, and NMP. Sustainability, 14(18), 10815. https://doi.org/10.3390/su141810815

Groysman, A. (2017). Corrosion problems and solutions in oil, gas, refining and petrochemical industry. Koroze a ochrana materialu, 61(3), 100.

Imtiaz, A., Othman, M. H. D., Jilani, A., Khan, I. U., Kamaludin, R., Iqbal, J., & Al-Sehemi, A. G. (2022). Challenges, opportunities and future directions of membrane technology for natural gas purification: a critical review. Membranes, 12(7), 646.

Jamekhorshid, A., Davani, Z. K., Salehi, A., & Khosravi, A. (2021). Gas sweetening simulation and its optimization by two typical amine solutions: An industrial case study in Persian Gulf region. Natural Gas Industry B, 8(3), 309–316. https://doi.org/10.1016/j.ngib.2021.03.005

Law, L. C., Yusoff, N., & Syamsul, S. R. (2018). Optimization and economic analysis of amine-based acid gas capture unit using monoethanolamine/methyl diethanolamine. Clean Technologies and Environmental Policy, 20(2), 451–461. https://doi.org/10.1007/s10098-017-1482-2

Liu, G., Zhu, L., Cao, W., Liu, H., & He, Y. (2021). New technique integrating hydrate-based gas separation and chemical absorption for the sweetening of natural gas with high H2S and CO2 contents. ACS Omega.

Mokhatab, S., Poe, W. A., & Mak, J. Y. (2015). Handbook of natural gas transmission and processing: Principles and practices (3rd ed.). Gulf Professional Publishing.

Rojey, A., Jaffret, C., Cornot-Gandolphe, S., Durand, B., Julian, S., & Valais, M. (1997). Natural gas: Production, processing, transport. Editions Technip.

Veawab, A., Tontiwachwuthikul, P., & Chakma, A. (2001). Corrosion behavior of carbon steel in the CO2 absorption process using aqueous amine solutions. Industrial & Engineering Chemistry Research, 40(22), 4771–4777. https://doi.org/10.1021/ie0100130

Zhao, F., Cui, C., Dong, S., Xu, X., & Liu, H. (2023). An overview on the corrosion mechanisms and inhibition techniques for amine-based post-combustion carbon capture process. Separation and Purification Technology, 304, 122091.

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Published

2025-12-10

How to Cite

Tare Caroline Gillow, Ipeghan J. Otaraku, Peter O. Muwarure, & Johnson Nnadikwe. (2025). Corrosivity Assessment of Hybrid Amine-Local Solvent Blends in Natural Gas Sweetening. Jurnal Teknik Indonesia, 4(02), 218–220. Retrieved from https://jurnal.seaninstitute.or.id/index.php/juti/article/view/785